在別人程式碼基礎上改的，163郵箱測試能用。

#!/usr/bin/env python
#coding=utf-8
'''
支援中文郵件的傳送
'''

from smtplib import *
from email.mime.text import MIMEText
from Tkinter import *
import tkMessageBox
import string


class loginPage(object):


    def __init__(self, master, info='Mail Send System'):
        self.master = master
        self.mainlabel = Label(master, text=info, justify=CENTER)
        self.mainlabel.grid(row=0, columnspan=3)


        self.user = Label(master, text='username', borderwidth=2)
        self.user.grid(row=1, sticky=W)


        self.pwd = Label(master, text='password', borderwidth=2)
        self.pwd.grid(row=2, sticky=W)


        self.userEntry = Entry(master)
        self.userEntry.grid(row=1, column=1, columnspan=2)
        self.userEntry.focus_set()


        self.pwdEntry = Entry(master, show='*')
        self.pwdEntry.grid(row=2, column=1, columnspan=2)


        self.loginButton = Button(master, text='Login', borderwidth=2, command=self.login)
        self.loginButton.grid(row=3, column=1)


        self.clearButton = Button(master, text='Clear', borderwidth=2, command=self.clear)
        self.clearButton.grid(row=3, column=2)


    def login(self):
        self.username = self.userEntry.get().strip()
        self.passwd = self.pwdEntry.get().strip()
        if len(self.username) == 0 or len(self.passwd) == 0 or '@' not in self.username:
            tkMessageBox.showwarning('警告', '使用者名稱或者密碼為空或郵件格式不正確')


            self.clear()
            self.userEntry.focus_set()
            return


        self.getSmtpHost()
        self.connect()


    def connect(self):
        'this method will try to connet the SMTP server according the current user'
        HOST = 'smtp.' + self.smtp +'.com'
        try:
            self.mySMTP = SMTP(HOST)
            self.mySMTP.login(self.username, self.passwd)
        #except SMTPConnectError:
        except Exception, e:
            tkMessageBox.showerror('連線錯誤', '%s' % e)
            return
        self.mySendMail = sendMail(self.master, self.mySMTP, self.username)


    def clear(self):
        self.userEntry.delete(0, END)
        self.pwdEntry.delete(0, END)


    def getSmtpHost(self):
        'this method try to obtian the SMTP HOST according the user account'
        firstSplit = self.username.split('@')[1]
        self.smtp = firstSplit.split('.')[0]




class sendMail(object):
    'my sendemail class'
    def __init__(self, master, smtp='', sender=''):
        self.smtp = smtp
        self.sender = sender


        self.sendPage = Toplevel(master)


        self.sendToLabel = Label(self.sendPage, text='send to:')
        self.sendToLabel.grid()
        self.sendToEntry = Entry(self.sendPage)
        self.sendToEntry.grid(row=0, column=1)


        self.subjectLabel = Label(self.sendPage, text='subject:')
        self.subjectLabel.grid(row=1, column=0)
        self.subjectEntry = Entry(self.sendPage)
        self.subjectEntry.grid(row=1, column=1)


        self.fromToLabel = Label(self.sendPage, text='from to:')
        self.fromToLabel.grid(row=2, column=0)
        self.formToAdd = Label(self.sendPage, text=self.sender)
        self.formToAdd.grid(row=2, column=1)


        self.sendText = Text(self.sendPage)
        self.sendText.grid(row=3, column=0, columnspan=2)


        self.sendButton = Button(self.sendPage, text='send', command=self.sendMail)
        self.sendButton.grid(row=4, column=0)


        self.newButton = Button(self.sendPage, text='new mail', command=self.newMail)
        self.newButton.grid(row=4, column=1)


    def getMailInfo(self):
        self.sendToAdd = self.sendToEntry.get().strip()
        self.subjectInfo = self.subjectEntry.get().strip()
        self.sendTextInfo = self.sendText.get(1.0, END)

    def sendMail(self):
        self.getMailInfo()
        content = self.sendTextInfo

        msg = MIMEText(content,_charset='utf-8')

        msg['Subject'] = self.subjectInfo
        msg['From'] = self.sender
        msg['To'] = self.sendToAdd
        smptSP = ('smtp.163.com',465)
        try:
            self.smtp.sendmail(self.sender,self.sendToAdd,msg.as_string())
            print u'傳送成功.........'  
        except SMTPException as e:
            print 'Error:',u'郵件無法傳送!\n',
        tkMessageBox.showinfo('提示', '郵件已傳送成功！')

    def newMail(self):
        self.sendToEntry.delete(0, END)
        self.subjectEntry.delete(0, END)
        self.sendText.delete(1.0, END)


if __name__ == '__main__':


    root = Tk()
    root.title('簡易傳送郵件程式')


    myLogin = loginPage(root)


    #root.wait_window(myLogin.mySendMail.sendPage)
    mainloop()