方式一：

  /// <summary>
        /// word檔案轉換二進位制資料(用於儲存資料庫)
        /// </summary>
        /// <param name="wordPath">word檔案路徑</param>
        /// <returns>二進位制</returns>
        public byte[] WordConvertByte(string wordPath)
        {
            if (!File.Exists(wordPath))
            {
                return null;
            }
            byte[] bytContent = null;
            System.IO.FileStream fs = null;
            System.IO.BinaryReader br = null;
            try
            {
                fs = new FileStream(wordPath, System.IO.FileMode.Open);
                br = new BinaryReader((Stream)fs);
                bytContent = br.ReadBytes((Int32)fs.Length);
                fs.Close();
                br.Close();
            }
            catch
            {
                fs.Close();
                br.Close();
                return null;
            }
            return bytContent;
        }

        /// <summary>
        ///二進位制資料轉換為word檔案
        /// </summary>
        /// <param name="data">二進位制資料</param>
        /// <param name="fileName">word檔名</param>
        /// <returns>word儲存的相對路徑</returns>
        public string ByteConvertWord(byte[] data, string fileName)
        {
            if (data == null) return string.Empty;

            FileStream fs = null;
            BinaryWriter br = null;
            try
            {
                fs = new FileStream(fileName, FileMode.OpenOrCreate);
                br = new BinaryWriter(fs);
                br.Write(data, 0, data.Length);
                br.Close();
                fs.Close();
            }
            catch
            {
                br.Close();
                fs.Close();
                return string.Empty;
            }
            return fileName;
        }

方式二：

   // <summary>
        /// 根據圖片路徑返回圖片的位元組流byte[]
        /// </summary>
        /// <param name="imagePath">圖片路徑</param>
        /// <returns>返回的位元組流</returns>
        private byte[] ImageToByte(string imagePath)
        {
            FileStream files = new FileStream(imagePath, FileMode.Open);
            byte[] imgByte = new byte[files.Length];
            files.Read(imgByte, 0, imgByte.Length);
            files.Close();
            return imgByte;
        }

        /// <summary>
        /// 位元組陣列生成圖片
        /// </summary>
        /// <param name="Bytes">位元組陣列</param>
        /// <returns>圖片</returns>
        private Image ByteArrayToImage(byte[] Bytes)
        {
            MemoryStream ms = new MemoryStream(Bytes);
            return Bitmap.FromStream(ms, true);
        }

　　程式執行效果：